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101.
Under the influence of previously published and some new theoretical results, potential‐ dependent adsorption and desorption of model electroinactive surfactants Triton X‐100 (T‐X‐100 or polyethylene glycol p‐(1,1,3,3‐tetramethylbutyl)‐phenyl ether) and sodium dodecyl sulfate (SDS) on the static mercury drop electrode (SMDE) were studied by square‐wave voltammetry (SWV). Although (according to the theory) the resulting current – potential curve should consist of two highly separated peaks, only desorption signal could be seen on each experimentally obtained voltammogram, most probably because of the limitations concerning the available potential range. Different properties of the recorded peak are in good agreement with the theory indicating that square‐wave voltammetry could be treated as a potential tool for tensammetric studies of electroinactive surface active substances. 相似文献
102.
103.
B. Visser M. Beck P. Bornhauser G. Knopp T. Gerber R. Abela J. A. van Bokhoven P. P. Radi 《Journal of Raman spectroscopy : JRS》2016,47(4):425-431
The potential of two‐color resonant and degenerate four‐wave mixing spectroscopy for investigations of the complex spectra of transition metal dimers is explored. Two‐color resonant and degenerate four‐wave mixing spectroscopy scans of the well‐known A‐X and B‐X transitions in Cu2 are reported and compared with previous experimental data obtained from standard single‐resonance techniques. The selectivity of the method is shown to enable the measurement of isotopologue pure spectra without the need for isotopically enriched metal targets. Specific subsets of the rovibronic structure are separated in a congested spectral region of overlapping transitions. The sensitivity of the method compares satisfactorily with linear spectroscopic methods such as laser‐induced fluorescence and cavity ring‐down. A new laser vaporization source for the production of transition metal dimers and clusters has been constructed. The new design aims for a high number density and maximum possible shot‐to‐shot stability. The possibilities of further applications of non‐linear four‐wave mixing spectroscopy to Cu2 and other transition metal dimers are discussed. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
104.
促进其线性频散特征另一种形式的Bousinesq方程 总被引:5,自引:1,他引:5
Bousinesq方程能够用于模拟表面重力波传播过程中的折射、绕射、反射以及浅化,非线性作用等现象.用不同垂直积分方法所得到的二维Boussinesq方程形式具有不同的线性频散特征.采用两个不同的水深层的水平速度变量组合,推导出一个新形式的Bousinesq方程.通过对其参数的设置可得到精确的线性频散解Pade近似4阶精度.其适用范围已由原来的浅水,向深水拓进.相速误差小于2%,其拓展适用范围可达到08个波长水深.应用所得到的新型Bousinesq方程,采用有限差分法,对经典工况进行了数值模拟,其计算结果表明,计算值与物模实验值吻合较好.这说明本文新形式的Boussinesq方程对变水深非线性效应所产生的能量频散有着较为精确的描述 相似文献
105.
The motion of fragments following disintegration of a meteoroid during its flight through the Earth's atmosphere is investiated.
Shock wave configurations, aerodynamical forces and moments acting on each fragment and the trajectories of the pieces are
determined for hypothetical initial configurations. The results of numerical simulations show that a meteoroid's breakup may
lead to both increase and decrease of the total cross section, drag forces and energy release in the atmosphere. As a consequence
the emitted radiation varies. 相似文献
106.
The paper studies the relationship between the physical characteristics of a cylinder and the properties of normal axisymmetric waves in elastic–liquid waveguides. The cylinder is made of a compliant material in which the velocity of shear waves is less than the sonic velocity in a perfect compressible liquid. The complete system of dynamic elasticity equations and the wave equation are used to describe the wave fields in the elastic cylinder and fluid, respectively. This approach allows obtaining the dispersion characteristics of coupled normal waves in compound waveguides over wide ranges of frequencies and wavelengths. The curves of real, imaginary, and complex wave numbers versus frequency are plotted for specific pairs of waveguide materials. Computations are carried out for a thick-walled cylinder filled with a fluid and immersed in either vacuum or a fluid. It is found out that compliant and rigid materials of the cylinder affect differently the wave interaction process in elastic–liquid waveguides 相似文献
107.
双驱动激波管稀疏波破膜技术研究 总被引:1,自引:0,他引:1
本文介绍了在双驱动激波管中运用稀疏波破膜的技术。在以压缩空气和氮气作实验气体的情形下,实验研究了中间段长度、稀疏波强度及中间段B膜的破膜压力(压差)对第二激波追韩第一激波的影响。实验结果表明:中间段的长短,显著地制约着前后两道激波的间隔;稀疏波强度及中间段B膜的破膜压力对稀疏波破膜时间及第二激小对反射稀疏波的追赶有重要影响。 相似文献
108.
On Free Nonlinear Vibrations of Fluid-Filled Cylindrical Shells with Multiple Natural Frequencies 总被引:1,自引:0,他引:1
Nonlinear free vibrations of a cylindrical shell fully filled with a perfect incompressible fluid are studied. The case is
examined where two natural frequencies of the shell are close
__________
Published in Prikladnaya Mekhanika, Vol. 41, No. 10, pp. 127–138, October 2005 相似文献
109.
P.J. Tan J.J. Harrigan Z. Zou S. Li 《Journal of the mechanics and physics of solids》2005,53(10):2174-2205
This study of the dynamic compressive strength properties of metal foams is in two parts. Part I presents data from an extensive experimental study of closed-cell Hydro/Cymat aluminium foam, which elucidates a number of key issues and phenomena. Part II focuses on modelling issues.The dynamic compressive response of the foam was investigated using a direct-impact technique for a range of velocities from 10 to . Elastic wave dispersion and attenuation in the pressure bar was corrected using a deconvolution technique.A new method of locating the point of densification in the nominal stress-strain curves of the foam is proposed, which provides a consistent framework for the definition of the plateau stress and the densification strain, both essential parameters of the ‘shock’ model in Part II. Data for the uniaxial, plastic collapse and plateau stresses are presented for two different average cell sizes of approximately 4 and 14 mm. They show that the plastic collapse strength of the foam changes significantly with compression rate. This phenomenon is discussed, and the distinctive roles of microinertia and ‘shock’ formation are described. The effects of compression rates on the initiation, development and distribution of cell crushing are also examined. Tests were carried out to examine the effects of density gradient and specimen gauge length at different rates of compression and the results are discussed. The origin of the conflicting conclusions in the literature on the correlation between nominal strain rate (ratio of the impact velocity Vi to the initial gauge length lo of the specimen) and the dynamic strength of aluminium alloy foams is identified and explained. 相似文献
110.